Tuesday, July 24, 2012

Stirring a bowl of honey is much more difficult than stirring a bowl of water. But why? The mass density of the honey is about the same as that of water, so we aren't moving more material. If we were to write out Newton's equation, ma would be about the same, but yet we still need to put in much more force. Why? And can we measure it?

The reason that honey is harder to stir is of course that the drag on our spoon depends on more than just the density of the fluid. The drag also depends on the viscosity of the fluid -- loosely speaking, how thick it is -- and the viscosity of honey is about 400 times that of water, depending on the conditions. In fact, a quick perusal of the Wikipedia article on viscosity shows that viscosities can vary by a fantastic amount -- some 13 orders of magnitude, from easy-to-move gases to thick pitch that behaves like a solid except on long time scales. The situation is even more complicated than this, as some fluids can have a viscosity that changes depending on the flow.

I wanted to find a way to measure the viscosities of the stuff around me, so I made the viscometer pictured below for about \$1.75 (the vending machines in Clark Hall are pretty expensive). How? Well, I

 My homemade viscometer, taking data on the viscosity of water.

1. Enjoyed the crisp, refreshing taste of Diet Pepsi from a 20 oz bottle (come on, sponsorships).
2. Cut the top and bottom off the bottle, so all that was left was a straight tube.
3. Mounted the bottle with on top of a small piece of flat plastic.
4. Mounted a single-tubed coffee stirrer horizontally out of the bottle (I placed the end towards the middle of the bottle to avoid end effects).
5. Epoxied or glued the entire edge shut.
6. Marked evenly-spaced lines on the side of the bottle.

I can load my "sample" fluid in the top of the Pepsi bottle, and time how long it takes for the sample level to drop to a certain point. A more viscous fluid will take more time to leave the bottle, with the time directly proportional to the viscosity. (This is a consequence of Stokes flow and the equation for flow in a pipe. It will always be true, as long as my fluid is viscous enough and my apparatus isn't too big.)

So we're done! All we need to do is calibrate our viscometer with one sample, measure the times, and then we can go out and measure stuff in the world! No need to stick around for the boring calculations! We can do some fun science over the next few blog posts!

But this is a physics blog written by a bunch of grad students, so I'm assuming that a few of you want to see the details. (I won't judge you if you don't though.) If we think about the problem for a bit, we basically have flow of a liquid through a pipe (i.e. the coffee stirrer), plus a bunch of other crap which hopefully doesn't matter much.

We first need to think about how the fluid moves. We want to find the velocity of the fluid at every position. This is best cast in the language of vector calculus -- we have a (vector) velocity field u at a (vector) position x. There are two things we know: 1) We don't (globally) gain or lose any fluid, and 2) Newton's laws F=ma hold. We can write these equations as the Navier-Stokes equations: $\vec{\nabla}\cdot \vec{u} = 0 \quad (1)$ $\ \rho \left( \frac {\partial \vec{u}} {\partial t} + (\vec{u}\cdot\vec{\nabla})\vec{u} \right) = - \vec{\nabla}p + \eta \nabla^2 \vec{u} \quad (2)$ The first equation basically says that we don't have any fluid appearing or disappearing out of nowhere, and the second is basically ma=F, except written per unit volume. (The fluid's mass-per-unit-volume is rho, the rate of change of our velocity is du/dt, and our force per unit volume is grad(p), plus a viscous term laplacian(u). The only complication is that du/dt is a total derivative, which we need to write as du/dt + du/dx*dx/dt.)

I won't drag you through the gory details, unless you want to see them, but it turns out that for my system the height of the fluid h (measured from the coffee stirrer) versus time t is $h(t) = h(0)e^{- t/T}, \quad T= 60.7 \textrm{sec} \times [\eta / \textrm{1 mPa*s}] \times [\textrm{ 1 g/cc} / \rho]$ [For my viscometer, the coffee stirrer has length 13.34 cm and inside diameter 2.4 mm, and the Pepsi bottle has a cross-sectional area of 36.3 square centimeters (3.4 cm inner radius). You can see how the timescale scales with these properties in the gory details section.]

 A run with measured heights vs times & error bars. The majority of the uncertainty turns out to come from not knowing the exact proportions of the viscometer. I don't know exactly why the heights are systematically deviating from the fit, but I suspect it's that my gridlines aren't perfectly lined up with the bottom of my viscometer (it looks like ~5 mm off would do it, which I can totally believe looking at the picture of my viscometer). However, because of the linearity of the equations for steady flow in a pipe, we know that the time scales linearly with the viscosity, so we should be able to accurately measure relative viscosities.
Well, how well does it work? Above is a plot of the height of water in my viscometer versus time, with a best-fit value from the equations above. To get a sense of my random errors (such as how good I am at timing the flow), I measured this curve 5 separate times. If I take into account the uncertainties in my apparatus setup as systematic errors, I find a value for my viscosity as $\eta \approx 1.429 \textrm{mPa* s} \pm 0.5 \% \textrm{Rand.} \pm 55\% \textrm{Syst.}$ The actual value of the viscosity of water at room temperature (T=25 C) is about 0.86 mPa*s, which is more-or-less within my systematic errors. So it looks like I won't be able to measure absolute values of viscosity accurately without a more precise apparatus. But if I look at the variation of my measured viscosity, I see that I should probably be able to measure changes in viscosity to 0.5% !! That's pretty good!

Hopefully over the next couple weeks I'll try to use my viscometer to measure some interesting physics in the viscosity of fluids.

1. This is really cool. However...

A FEW IMPROVEMENTS TO YOUR EXPERIMENTAL DESIGN

1. It is not clear what the fluid is flowing into/onto. When measuring the viscosity of delicious fluids, I recommend placing a bowl of ice cream under the apparatus to prevent needless loss.

That is all.

1. Can you help me with this?
I need more details on this design

2. My old boss joked once in his grad-level polymer physics class that all you needed to measure viscosity was "a stopwatch, a balance, and a handy gravitational field." One of the grad students asked "where could I buy a gravitational field?"

Anyway, the above method is actually something that some of the polymer companies making polyethylene and polypropylene do to get a rough idea of the molecular weight by measuring the viscosity at a specific temperature.

C

3. @ Corky: The best part of your comment is that I was collecting my fluid in an empty ice cream bucket.

@ C: I was thinking of using a balance, but I figured taht drawing lines on a sheet of paper was cheaper :). Also, I'd like to shove some polymer (or something) in it in the near future and show these kind of dependencies.

4. Water, honey, ice cream... and what about beer ?
Beer bong is a good homemade viscometer ^^

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6. This is really great. Thesis Writing

7. I'm fascinated by this topic. Thanks for a great post! Very interesting to learn another way to measure viscosity without expensive instruments.

8. Nice post, I bookmark your blog because I found very good information on your blog, Thanks for sharing more information clik more

9. Yay for spam. :P
Otherwise, neato. Interestingly enough this is the first place where I found nice, neat collected information on a simple way to measure viscosity. All other ways ended up being... not simple and/or easy to recreate.
Thanks a lot. :)

10. Some of the specific details and pictures seem to be missing. Could you make them accessible again?

11. This is my first time i visit here. I found so many entertaining stuff in your blog. Keep up the good work.
Plastic Flow Meter

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